Influence of ligand geometry on the formation of In-O chains in metal-oxide organic frameworks (MOOFs).

Effect of the pillar ligand on preventing agglomeration of ZnO nanoparticles prepared from Zn(II) metal-organic frameworks

Metal-Organic Frameworks (MOFs) represent a new class of highly porous materials. On this regard,  two nano porous metal-organic frameworks of [Zn2(1,4-bdc)2(H2O)2∙(DMF)2]n (1) and [Zn2(1,4-bdc)2(dabco)]·4DMF·1⁄2H2O (2), (1,4-bdc = benzene-1,4-dicarboxylate, dabco = 1,4-diaza...

Synthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors

Copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [Cu3(btc)2] (1) and [Cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°C. It has also been found that the reaction temperature pla...

Metal-organic frameworks of cobalt and nickel centers with carboxylate and pyridine functionality linkers: Thermal and physical properties; precursors for metal oxide nanoparticle preparation

This  article  provides  an  overview  on  preparation,  design,  crystal structure  and  properties  of  some  metal-organic  frameworks  of carboxylate coordination polymers mixed with pyridine-functionality linkers  prepared  in  our  laboratory.  The  article  covers  coordination polymers  in  two-  and  three-dimensional  supramolecular architectures. The reported coordination polyme...

In this paper, the effect of nanocatalytic metal-organic framework based on copper metal and bis-tetrazolamine (CuBTA) ligand functionalized with cobalt (II) oxide nanoparticles on the thermal decomposition behavior of ammonium perchlorate (AP), using differential survey calorimetry (DSC) has been reviewed. First, the metal-organic framework (CuBTA) was synthesized from the raw materials of cop...

Synthesis, characterization, antibacterial activity and molecular modeling studies of Ni(II) and Zn(II) complexes with phenylpyridylformamidine ligand

The Ni(II) and Zn(II) complexes with phenylpyridylformamidine (PhPyF) ligand, [Ni(PhPyF)Cl2] and [Zn(PhPyF)Cl2], have been prepared and investigated using different chemical techniques such as elemental analysis, molar conductance, FT-IR, UV-vis spectra and magnetic moment. The obtained chemical analysis data showed the formation of 1:1 (metal: ligand) ratio. The square planar and tetrahedral g...